MacDermid Enthone Industrial Solutions Technical Journeys

Imagen de las 19 Jornadas MacDermid

In an increasingly dynamic environment, in which changes are constantly occurring and everything is evolving rapidly towards increasingly effective and productive solutions that encompass all the processes that can occur within companies, it is essential to have high-level suppliers that are a perfect partner in this journey.

On this occasion, the MacDermid Enthone Industrial Solutions team visited our facilities to give us a presentation of the latest developments in the current market and, on the other hand, to set our sights on the near future with new coatings for sectors such as the electric car.

This conference was of great interest for our company, as not only ideas for new processes were gathered, but also solutions for such important chapters for us as purification and environment, in which we are putting a great effort and which has become one of our basic pillars in our strategic plan.

Many thanks to MacDermid Enthone Industrial Solutions for their visit and presentation.

Information Next Generation Funds for the installation of solar panels

 

On 29 June 2021, the Council of Ministers, at the proposal of the Ministry for Ecological Transition and the Demographic Challenge, approved Royal Decree 477/2021 for the implementation of various incentive programmes linked to self-consumption and storage, with renewable energy sources, as well as the implementation of renewable thermal systems in the residential sector, within the framework of the Recovery, Transformation and Resilience Plan, financed by the European Union – NextGenerationEU, Recovery and Resilience Mechanism (EU Regulation 2021/241 of 12 February 2021).

The objective of Royal Decree 477/2021 is to promote the deployment of renewable energies, both thermal and electrical, in the different consumer sectors, to encourage greater control of consumption through the development of behind-the-meter storage systems and the promotion of industry and the associated business sector, through six incentive programmes for self-consumption, storage and thermal uses of renewable energies:

  • Incentive programme 1: Implementation of self-consumption installations, with renewable energy sources, in the services sector, with or without storage.
  • Incentive programme 2: Implementation of self-consumption installations, with renewable energy sources, in other productive sectors of the economy, with or without storage.
  • Incentive programme 3: Incorporation of storage in self-consumption installations, with renewable energy sources, already existing in the services sector and other productive sectors.
  • Incentive programme 4: Implementation of self-consumption installations, with renewable energy sources, in the residential sector, public administrations and the third sector, with or without storage.
  • Incentive programme 5: Incorporation of storage in self-consumption installations, with renewable energy sources, already existing in the residential sector, public administrations and the third sector.
  • Incentive programme 6: Implementation of thermal renewable energy installations in the residential sector.

You can then access Inelca’s strategic plan for the photovoltaic solar installation project through the following link:

Installation of Photovoltaic Panels

INELCA inelca_instalación de placas fotovoltaicas

As an electro-intensive company, energy consumption is one of the most important factors in our activity.

For this reason, we are committed to renewable energies with the installation of photovoltaic panels on the roof of our warehouse. This project has been one of the largest investments for Inelca in 2022.

The installation of photovoltaic panels allows us to reduce the economic energy costs due to the reduction of consumption supplied by the electricity company and on the other hand we contribute to the improvement of the environment by reducing emissions into the atmosphere and the carbon footprint.

The latter is another of Inelca’s main pillars, the preservation of and respect for the environment.

Keys to selecting a good coating applicator

Article courtesy of Atotech (www.atotech.com)

Authors:

Steve Kocka: General Manager General Metal Finishing North America at Atotech USA LLC

Markus Ahr: Global Product Manager Corrosion Protection Coatings, Atotech

 

Selecting the right electroplating applicator can be as challenging as producing the part. These are the key considerations to ensure a quality finish and reasonable delivery.

As the industrial world continues to evolve, the need for metal surface coatings also changes. The challenges posed by the end owner of a given part become more complex. There are several points to consider when choosing the appropriate finish applicator.

Just as there are different levels of quality among metal fabrication and metalworking facilities, there are also many different levels among applicators in the coating world. Choosing the right coater is an important step that is often overlooked in the final stage of manufacturing. To get the job done right, there are a few basic points to consider:

  • Logistics: Logistics can play an important role. In some cases, the location of the finishing supplier is critical as transportation influences the final cost of the finished part. Some applicators have their own fleet of trucks.
  • Organic versus inorganic: Requiring organic finishes (paint) or inorganic finishes can have an impact on the choice of the most suitable applicator for the job. The selection of a coater that meets the quality requirements as well as the final OEM specification is an important consideration. The size of the parts to be processed can also be a limiting factor. Does the part fit in the paint booth / tank / cataphoresis tank…? Some OEMs specify very specific process chemistry, and not all applicators will have those finishes or chemistries. Thoroughly examine the capabilities of the coater before committing to the job.
  • Coatings: These days, a single layer of coating is often not enough to meet the end user’s decorative or corrosion criteria. This is where things get more complicated. Finding an applicator that can provide both organic and inorganic finishes is a key element in this area. As an example, the finish can be an electrolytic zinc or zinc/nickel coating, followed by a RoHs-compliant trivalent passivate, an inorganic finish such as cataphoresis, powder coating, wet painting, adhesives (rubber bonding) or zinc flakes, all of these possible combinations of coatings offer completely different aspects and properties to what a single layer coating can offer. Working with an applicator whose chemical supplier has all the necessary finishes will prevent us from being held responsible if coating problems arise.
  • Thickness: The final coating thickness specification is also a critical element when choosing an applicator. To apply dip/spin zinc flake coatings, appropriate equipment is needed to minimise build-up on the head or thread (for fasteners) or to avoid blocking threaded blind holes. Not all applicators have such application equipment available.
  • Quality: Does the applicator have a quality system? Accreditations such as CQI (GM) or DIN EN ISO 9001, IATF 16949, etc. can provide the necessary level of quality. Not all applicators have advanced quality systems in place.
  • Part assembly: If a part is to be assembled with another part from a different origin or process, decorative concerns such as “colour matching” or functional concerns such as “galvanic corrosion concerns” may arise. A typical example in the automotive industry is assembling aluminium structures using coated steel screws.
  • Testing: The applicator should have access to a technical centre where he/she can apply and compare various types of coatings for evaluation, as well as be able to perform the required corrosion and coefficient of friction tests.
  • Equipment: does the applicator have all the necessary equipment or will he need to incorporate new special equipment? Some applicators make their own accessories, which can optimise production times and add value to the supply chain by completing more steps in one place.
  • Coating supplier: In some cases, the company that supplies the chemistry and materials for the coating to the applicator may have significant resources at its disposal:
    • In-house technical centres with the capacity to process large parts, thus being able to provide real production samples with a variety of coating processes.
    • Analytical and metallurgical laboratories that can examine surface conditions as well as analyse processes, assisting in both defining a process and identifying the causes of potential defects.
    • Multiple coating capabilities, which can offer the OEM or Tier the opportunity to explore all types of coatings or, in some cases, coatings that combine organic and inorganic materials.
    • A catalogue of already proven single and multiple coating finishes, with their known properties, which will provide preview results and assist in faster design of the final finish.
    • Global services, which allow “copy-paste” of the desired finishing systems already being applied in other parts of the world, thus obtaining uniform results in the supply chain.
    • Global audit programme, which guarantees a standardised quality system for the coating industry, which will be well received by Tiers and OEMs.
    • Customised training courses on the possibilities and limitations of coating systems for OEMs and TIERs to develop the ability to distinguish and evaluate different levels of quality.

When faced with the challenge of defining a coating type as well as a network of applicators that meets the needs of the production process, involving the coating chemistry manufacturer in the process can often shorten the market entry cycle.

Evaporation: Environmental solution

Imagen manos y agua para Evaporación: Solución medioambiental

As part of Inelca’s continuous effort to minimise the environmental impact of its activity, our company has incorporated a mechanical compression evaporator for the treatment of waste water from the Zinc Nickel (ZnNi) processes.

The incorporation of this water treatment technology is intended to cover several objectives:

  • Minimisation of water consumption: By means of the mechanical compression evaporation technique, water consumption is reduced by up to 97 %.
  • Reduction of environmental impact: By reusing up to 97 % of the water treated in the evaporator, the environmental impact of this volume is reduced, approaching zero discharge.
  • Robustness: The evaporation processes make the purification process robust and reliable.
  • Water quality: The water obtained after the evaporation process improves the quality of the mains water, giving greater stability to the production processes.

After one year of operation, the conclusions are positive and all the established objectives have been met. Despite being a considerable investment, the results obtained endorse and justify it.

Post-pandemic economic situation in the electroplating sector

After more than a year of trying to overcome the serious problems caused by the pandemic, and when it seems that the clouds are beginning to clear with the immunisation of the population through the vaccine, new obstacles are appearing on the horizon in the industrial sector that only hinder the exit of companies.

Focusing on the automotive sector, one of the main sectors of the electroplating industry, more than 231,000 vehicles have not been produced in Spanish factories so far this year. One of the main reasons for this is the worldwide shortage of semiconductors, and it seems that a solution to the problem is not in sight until 2022.

To this problem must be added the huge increase in the price of raw materials such as metals, chemicals and oil, which is not only affecting the cost of plastic materials, but also energy and logistics costs, as in the case of sea freight, the cost of which has increased fivefold. The high electricity prices we are seeing and the regulatory changes in the electricity bill that came into force this June are not helping companies either, further damaging their bottom line.

There have been several reasons for these increases: the increase in demand for raw materials due to the gradual recovery of the markets after Covid-19, the tendency of companies to over-stock to avoid stock-outs, the reactivation of the Chinese and US economies, which has led to a lower flow of materials to Europe, and the 35% drop in Europe’s steel production capacity.

For all these reasons, the Spanish automotive supplier industry is now facing a crisis derived from the lack of raw materials and rising costs, which is holding back the path of recovery it was starting on.

There is now talk of higher than desired inflation, but anyone who knows the automotive sector knows how difficult it is to raise any price increase derived from cost increases with the manufacturer, especially when it is at the end of the production chain as a treatment supplier, so it is they who are bearing these increases at the expense of their profitability, putting the viability of the projects at risk.

Electrodeposition

Electrodeposición imagen abeja INELCA

Electrodeposition is the phase of the electrolytic treatment where the parts are coated with a thin layer (microns) of the metal or alloy that we want to deposit.

To do this, the parts are immersed in an electrolytic solution, called electrolyte, which contains ions of the metal or metals that will form the layer.

A galvanic system is created in which we have an anode, a cathode (the parts to be coated are those that act as a cathode), the electrolyte, where the ions of the metal to be deposited are (Zn, Fe, Ni, …), and a source of direct current that provides electrons, by means of which the reaction of reduction of the metal ions is produced, to be transformed into metal, on the surface of the parts to be coated.

A simple diagram of this galvanic system would be as follows:

Electrodeposición esquema INELCA SLU

The main factors that influence the correct formation of the coating layer are:

  • State of the surface to be coated.
  • Composition of the electrolyte.
  • Conductivity of the system.
  • Applied current density.
  • Working temperature of the electrolyte.
  • Agitation and filtration of the electrolyte.

All these parameters are controlled at INELCA according to our control plans.

Prevention & Innovation

The spread of the Covid-19 pandemic has forced us to quickly alter our habits. It is now up to companies to ensure compliance with rules of conduct that allow safe activity. That is why INELCA, aware of the culture of prevention and complying with the Law on the Prevention of Occupational Risks, has incorporated the procedure for action and contingency plan for the Covid-19.

We believe and understand that the multiple measures and actions applied for the safety of the employees, are not temporary measures but a structural change that comes to stay for a long time. And it is in this new framework where innovation can help us and where we have chosen to install temperature detection and access control solutions for early prevention as containment measures. Solutions with high thermographic reliability together with functionalities provided by artificial intelligence providing security, precision and speed. All aimed at a clear and unique objective: the safety of all our employees.

Preparation/Cleaning

For a correct application of any surface treatment, the state of the surface on which it is to be applied is essential.

Because the parts on which the coating is to be applied come from previous processes (stamping, machining, threading, heat treatment, etc…), they must be subjected to cleaning processes prior to the deposition of the coating, otherwise we may find problems of adhesion or even non-coating. This is what is called the preparation phase within the coating processes.

Within the coatings that we apply at INELCA, we can differentiate between two large groups, electrolytic (Zn,ZnNi, ZnFe) and non-electrolytic (Zn flakes), and each of them has a different type of preparation:

Electrolytic:

The preparation phase of electrolytic coatings consists mainly of three stages: chemical degreasing, electrolytic degreasing and pickling.

i)Chemical degreasing: This is an alkaline phase, normally based on soda, responsible for eliminating the oils from the mechanisation of the parts or from the threading processes.

ii)Electrolytic degreasing: This is an alkaline phase, normally based on soda, in which the cleaning effect of the chemical degreasing is added to the mechanical action due to the generation of gas on the surface of the part. This gas is generated by a chemical reaction when an electric current is applied. Thanks to this mechanical action, it is possible to clean up oil residues occluded in the pores of the parts.

iii)Pickling: This is an acidic phase in which metal remains and oxides present in the parts are eliminated, both those that come from natural oxidation and those that may be produced in heat treatments.

In this phase the intermediate coatings for storage that the pieces can have are also eliminated.
The most common acids used in this phase are hydrochloric or sulphuric, to which inhibitors are added to prevent over-attacking of the parts and to minimise possible hydrogen embrittlement.

Zn flakes:

Zn flakes processes, to avoid hydrogen embrittlement processes, have a different preparation. The most common consists of chemical degreasing and shot blasting.

i)Shot blasting: Mechanical cleaning process that consists of projecting abrasive material onto the parts.

Corrosion tests II: Most common types of tests

Imagen para enseyosde corrosión INELCA SLU

In the previous instalment of this publication we saw the definition, purpose and limitations of corrosion tests, in this instalment we will discuss the most widespread types of corrosion tests used to test metal parts coated with sacrificial metals such as Zn, ZnFe, ZnNi and Zn flakes.

SST:

The initials of this test correspond to the Salt Spray Test, currently it is perhaps the most extensive test to evaluate the quality of coatings deposited on steel parts. It consists of introducing the pieces to be tested in a chamber that is filled with mist by means of a nebulizer formed from a solution of distilled water with 5% NaCl (salt), with humidity, temperature and pH of the chamber under standardized parameters. The permanence within the SST will depend on the type of coating to be tested and the specification established by the end user of the parts. During the test, which can go from 24 h to 3000 h or more, the condition of the samples is evaluated every 24 h, and both the corrosion of the coating (WR: white rust) which will appear first, and the corrosion of the steel (RR: Red rust)

Climatic tests:

As we discussed in the previous instalment, corrosion tests cannot be correlated with the useful life of the piece-coating assembly, in order to bring the time of use and test relationship closer several years ago the automotive sector began to specify climatic tests on treated parts. For this, each manufacturer defined a unique test cycle tailored to their needs, thus creating another type of corrosion test: Climate Tests. These tests consist of cycles of usually 24 hours (1 cycle) consisting of subjecting the samples to a sequence of climatic conditions of humidity, SST and sudden temperature changes. The permanence of the samples in the climatic test chambers will depend on the applied coating, the specification of the end user and the type of test defined by each OEM, ranging from 1 to 30 cycles or more.